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Anne 'Annie' Mack ( Meredith Bishop) Alex's older sister, and a scientific genius in her own right.He has proven numerous times that he will do anything to protect Alex from the Plant. Alex sees him as her brother, often sharing everything between themselves, including the secret of Alex's powers. Raymond 'Ray' Alvarado ( Darris Love) – Alex's closest friend and next-door neighbor.

After the chemical accident on her first day of Junior High, Alex must now deal with the pressures of having extraordinary abilities in addition to the normal struggles of her everyday life. Alexandra 'Alex' Mack ( Larisa Oleynik) – Alex is an average teenager in Paradise Valley.She confides only in her sister Annie and her best friend Raymond about her powers and must keep them a secret from everyone else, including her parents, for fear of what the chemical plant CEO, Danielle Atron, will do to her if she finds out. She also turns golden yellow when experiencing extreme emotions, a source of much anxiety. She now has the power of telekinesis, can shoot electricity through her fingertips, and morph into a silver puddle. It's not long after when Alex realizes the chemical has done something to her. After her first day of junior high school, while walking home, Alex is nearly hit by a truck from the chemical plant, and during the incident, she is drenched with a top-secret chemical called GC-161. Alex Mack is an ordinary teenage girl, living with her parents and older sister in the corporate town of Paradise Valley.

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